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Tert-butyl hydroperoxide TBHP-70 CAS 75-91-2
Description
- CAS: 75-91-2
- Synonyms: Tert-butyl hydroperoxide,TBHP-70
- Einecs: 200-915-7
- Molecular Formula: C4H10O2
- Grade: 69.0-71.0%
- Package: 25kg/drum or as required
Details
Tert-butyl hydroperoxide TBHP-70 is Colourless, mobile liquid consisting of ca. 70 % tert.Butylhydroperoxide, de-sensitised with water. This alkyl-hydroperoxide is used as an initiator for the polymerisation of monomers, e.g. ethylene, vinyl acetate or (meth-) acrylates.Due to its oxidation potential TBHP-70-AQ is used as oxidizing agent in numerous chemical syntheses.
Specification:
| Appearance | colourless liquid |
| Assay | 69~71% |
| Active oxygen (AO) | 12.25% min |
| Density at 20 °C | 0.896~0.93 g/cm3 |
| Refractive index at 20 °C | 1.385~1.389 |
| Density at 20°C | ca. 1.04 g/cm3 |
| Color/Hazen | ≤20 |
| pH(20 °C) | 4.5~9 |
| Self-Accelerating Decomposition Temperature (SADT) | >80 °C |
| Recommended storage temperature | 2 to 35 °C |
| Storage stability as from date of production | 12 months |
Half-life Data :
10 h / 1 h / 1 min (benzene, 0.1 mol/L) 170 °C / 195 °C / 260 °C
Decomposition Products:
Possible detectable decomposition products: tert.Butyl alcohol, acetone,methane.
Application:
EMULSION POLYMERISATION:
Initiator for the emulsion polymerisation of vinyl acetate, (meth-) acrylates andacrylic resin paint dispersions in combination with suitable reducing agents (Fe-salts, sulphites, dithionites, rongalite, ascorbic acid or sugar).
Temperature range: 50 – 80 °C .
Dosage level: 0.1 – 0.5 % as supplied.
Particularly suitable for reduction of residual monomer.
COPOLYMERISATION:
Initiator for the copolymerisation of styrene / butadiene or acrylnitrile /butadiene / styrene in emulsion. In combination with redox systems polymerisation temperatures are possible between 5 and 25 °C.
Dosage level: 0.1 – 0.3 % as supplied
CHEMICAL SYNTHESIS:
Selective oxidizing agent for hydrocarbons, olefins, alcohols, etc.
Storage:
Avoid any source of heat and light and protect the product from impurities. Keep within save temperature limits.
Package:
(1)25 kg in HDPE canister
(2)190 kg drums
(3)1000 kg drums
FAQ
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Q: How to buy and get more information such as COA, TDS, MSDS?A: You can download the file in Support or contact info@blitchem.com to get it.
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